Thermal decomposition of cyclohexane by flash pyrolysis vacuum ultraviolet photoionization time-of-flight mass spectrometry: a study on the initial unimolecular decomposition mechanism
نویسندگان
چکیده
Cyclohexane decomposes mainly via C–C bond rupture producing 1,6-hexyl diradical. The diradical leads to 1-hexene and can also directly dissociate. C6H12 does not decompose ?C6H11 + H. Benzene be formed sequential H2 eliminations of C6H12.
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2021
ISSN: ['1463-9076', '1463-9084']
DOI: https://doi.org/10.1039/d1cp00459j